Product ID:PERMA-STEEL SHOT
MSDS Date:10/21/1991
FSC:5350
NIIN:00N042808
MSDS Number: BSXZS

NATIONAL METAL ABRASIVE INC

142 AUBLE ST
WADSWORTH, OH 44281-1739
US

Emergency Phone: 216-334-1566

Info Phone: 216-334-1566

Cage: 42736

NATIONAL METAL ABRASIVE INC

WADSWORTH, OH 44281-1739 US

Telephone: 216-334-1566

Cage: 42736

MANGANESE (SARA III). (PERCENTAGE 0.5-1.3)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 1.3%

OSHA PEL 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 C

CARBON BLACK; (CARBON). (PERCENTAGE 0.8-1.3)

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1.3%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

SILICON. (PERCENTAGE 0.4-1.2)

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 1.2%

OSHA PEL 10 MG/M3 TDUST

ACGIH TLV: 10MG/M3 TDUST;5 RESP

CLASSED AS A HAZ WASTE AND AS SUCH, MUST BE

RTECS: 9999999ZZ

>1371C, >2403F.

RTECS: 9999999ZZ

IRON (III) OXIDE

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: > 96%

OSHA PEL 5 MG/M3 (FE)

ACGIH TLV: 5 MG/M3 (FE)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF DUST CREATED DURING USE;
SHOT, GRIT OR DUST PARTICLES IN EYES. PROLONGED OVEREXPOSURE TO
MANGANESE DUST OR FUME CAN CAUSE METAL FEVER. CHRONIC OVEREXPOSURE
CAN CAUSE MANGANESE POISONING. OVEREXPOSURE TO DUST CONTAINING THE
COMPONENT ELEMENTS OF CAST STEEL ABRASIVE MAY CAUSE SKIN, NOSE,
MOUTH & EYE IRRIT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH WITH RUNNING WATER FOR AT LEAST 15 MIN TO REMOVE
PARTICULATE. GET ADDITIONAL ATTENTION BY A QUALIFIED MEDICAL
PERSON. SKIN: BRUSH OFF EXCESS DUST. WASH AREA WELL WITH SOAP AND
WATER. INHAL: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGEST:
SEEK MEDICAL HELP IF LARGE QUANTITIES OF MATERIAL HAVE BEEN
INGESTED.

Extinguishing Media:USE DRY CHEMICALS OR SAND TO EXCLUDE AIR.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:SOLID FORM IS NOT COMBUSTIBLE. FIRE/EXPLO
HAZ MOD WHEN IN DUST FORM/EXPOSED TO HEAT/FLAME/CHEMICAL
REACTION/CONTACT WITH POWERFUL OXIDIZER.

Spill Release Procedures:CAST STEEL SHOT OR GRIT SPILLED OR LEAKED ONTO
FLOORS CAN CAUSE HAZ WALKING CNDTNS. SPILLS OR LEAKS SHLD BE
VACUUMED OR SWEPT FORM WORKING AREAS. WHEN CLEANING UP LRG QTYS OF
DUST, NIOSH/MSHA APPRVD R ESP SHLD BE WORN. SPILLED SHOT & GRIT
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE MATL AWAY FROM INCOMPATIBLE
MATERIALS, AND KEEP DUST AWAY FROM SOURCES OF IGNITION. KEEP DRY TO
REDUCE RUSTING.
Other Precautions:OBSERVE MAXIMUM FLOOR LOADING LIMITATIONS. THE
COMPANY HAS NO CONTROL OVER THIS PRODUCT OR ITS USE AFTER IT LEAVES
OUR FACILITY. THE COMPANY ASSUMES NO LIABILITY FOR LOSS OR DAMAGE
FROM THE PROPER OR IMPROPER USE OF THIS PROD.

Respiratory Protection:IF THE DUST CREATED BY USE EXCEEDS THE TLV'S
INDICATED IN INGRED SECTION, A NIOSH/MSHA APPROVED RESPIRATOR
SHOULD BE WORN.
Ventilation:GENERAL AND LOCAL EXHAUST VENTILATION SHLD BE PROVIDED TO
KEEP THE DUST LEVELS BELOW TLV'S SHOWN IN INGREDIENT SECTION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:APPROVED SAFETY GLASSES W/ EYE SHIELDS.
Other Protective Equipment:SAFETY EYEWASH STATIONS SHOULD BE PROVIDED
IN CLOSE PROXIMITY TO WORK AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
APPEAR & ODOR: COLOR W/SLIGHT METALLIC ODOR. BOILING PT: >2850C,>5162F.
SPILL PROT: CAN BE RECLAIMED FOR REUSE OR DISPOSED OF AS A NON-HAZ
SOLID WASTE. COLLECTED DUST FROM BLAST CLEANING/ SHOT PEENING
OPERATIONS ALWAYS CONTAIN CONTAM FROM THE SURFACE OF THE PARTS
BEING PROCESSED, & THEREFORE THE DUST MAY BE (ING 5)

HCC:N1
Boiling Pt:B.P. Text:SUPP DATA
Melt/Freeze Pt:M.P/F.P Text:ING 6
Spec Gravity:>7.6 @ 60F
Appearance and Odor:SHOT IS NEAR SPHERICAL. GRIT IS ANGULAR. BOTH ARE
GREY TO BLUE IN (SUPP DATA)

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE. SHOT AND GRIT WILL BREAK DOWN
INTO PROGRESSIVELY SMALLER PARTICLES DURING NORMAL USE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.